Exploration of electron-vibrational interaction in the 5d states of Eu²⁺ ions in ABaPO₄ (A = Li, Na, K and Rb) phosphors

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• 作者：Govind B. Nair ; P. D. Bhoyar and S. J. Dhoble
• 刊名：Luminescence
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：32
• 期：1
• 页码：22-29
• 全文大小：789K
• ISSN：1522-7243

文摘

This work reports the theoretical analysis of the electron–vibrational interaction (EVI) in 4f–5d optical transitions of Eu²⁺ ions in ABaPO₄ (A = Li, Na, K and Rb) systems. The EVI parameters were estimated from the recently reported room temperature photoluminescence results, by employing the spectrum-fitting method. Parameters such as the Huang–Rhys factor, effective phonon energy, Stokes shift and zero-phonon line position were estimated and are reported here. The estimated EVI parameters were validated by modeling the emission band and establishing the agreement between the experimental and modeled emission bands. Copyright