Hypervalent Iodine(III)-Mediated Oxidative Fluorination of Alkylsilanes by Fluoride Ions

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• 作者：Peng Xu ; Feng Wang ; Guilan Fan ; Prof. Xiufang Xu and Prof. Pingping Tang
• 刊名：Angewandte Chemie International Edition
• 出版年：2017
• 出版时间：January 19, 2017
• 年：2017
• 卷：56
• 期：4
• 页码：1101-1104
• 全文大小：634K
• ISSN：1521-3773

文摘

The first example of a hypervalent iodine(III)-mediated oxidative fluorination of alkylsilanes by fluoride ions without the use of transition metals is demonstrated. This reaction is operationally simple, scalable, and proceeds under mild reaction conditions. Mechanistic studies suggest the involvement of a single-electron transfer resulting from the interaction of an organopentafluorosilicate and aryliodonium difluoride, which were generated in situ from the corresponding alkylsilane and iodosobenzene, respectively, in the presence of fluoride ions.