Palladium-Catalyzed Carbonylative Synthesis of 3-Methyleneisoindolin-1-ones from Ketimines with Hexacarbonylmolybdenum(0) as the Carbon Monoxide Source

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• 作者：Zechao Wang ; Fengxiang Zhu ; Yahui Li and Prof. Dr. Xiao-Feng Wu
• 刊名：ChemCatChem
• 出版年：2017
• 出版时间：January 9, 2017
• 年：2017
• 卷：9
• 期：1
• 页码：94-98
• 全文大小：432K
• ISSN：1867-3899

文摘

An interesting procedure for the palladium-catalyzed carbonylative synthesis of 3-methyleneisoindolin-1-ones from ketimines was established. By using Mo(CO)₆ (0.3 equiv.) as the solid CO source and through C(sp²)−H bond activation, the desired 3-methyleneisoindolin-1-ones were isolated in moderate to good yields.