UV/VIS-investigation of V(III) complexes with biomimetic ligands - elucidation of coordination numbers without knowing the crystal structure

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• 作者：Meier ; R. ; Boddin ; M. ; Schö ; nherr ; T. ; Schmid ; V.
• 刊名：Journal of Inorganic Biochemistry
• 出版年：1995
• 出版时间：August, 1995
• 年：1995
• 卷：59
• 期：2-3
• 页码：597
• 全文大小：49.1 K

文摘

X-ray structure determinations of V(III) chelates with aminopolycarboxylic acids have shown that coordination number seven (CN 7) is adopted more frequently than expected. During related structural studies of V(III) complexes belonging to the same class (edta-type complexes), coordination number six was also found.