Rhodium-BiPhePhos catalyzed hydroformylation studied by operando FTIR spectroscopy: Catalyst activation and rate determining step

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• 作者：Andreas J&ouml ; rke^a ; ^{andreas.joerke@ovgu.de} ; Andreas Seidel-Morgenstern^a ; ^b ; Christof Hamel^a ; ^c
• 关键词：BiPhePhos ; 1-Decene ; Hydroformylation ; Rhodium
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PA
• 页码：10-14
• 全文大小：2821 K
• 卷排序：426

文摘

No significant formation of inactive or non-selective Rh-species using BiPhePhos. First order dependence of the hydroformylation with respect to olefin concentration. Olefin coordination to the Rh-catalyst is determining the hydroformylation rate.