Half-metallicity and magnetism of quaternary Heusler compounds CoRuTiZ (Z=Si, Ge, and Sn)
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The CoRuTiZ Heusler compounds are half-metals at their equilibrium volumes.

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The E<sub>gsub> values are 0.13, 0.10, and 0.01 eV for Z=Si, Ge, and Sn, respectively.

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The half-metallicity originates from d-d and covalent hybridizations.

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The M<sub>totsub> of CoRuTiZ compounds obey the slater-pauling rule (M<sub>totsub>=Z<sub>totsub>&minus;24).

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The widest region of half-metallicity belongs to CoRuTiSi (about 0.59 Å).

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