Incorporation of IL effectively improves sensitivity of GNS/Pd toward glucose.
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BMP–DCA IL effectively improves sensitivity of GNS/Pd toward ascorbic acid.
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Selective detection is achieved using a non-enzymatic electrode with designated IL.
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GNSs can render an aligned cation/anion orientation in the adsorbed IL film.
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IL anions occupy the topmost electrode surface, determining the selectivity.
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