Thermal behaviour below and inside the glass transition region of a submicron P3HT layer studied by fast scanning chip calorimetry

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Thermal behaviour below and inside the glass transition region of a submicron P3HT layer studied by fast scanning chip calorimetry

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作者：N. Van den Brande ; G. Van Assche ; B. Van Mele ; ^{bvmele@vub.ac.be" class="auth_mail" title="E-mail the corresponding author}
关键词：Isothermal crystallization ; Organic photovoltaics ; Two-step nucleation
刊名：Polymer
出版年：2016
出版时间：28 January 2016
年：2016
卷：83
期：Complete
页码：59-66
全文大小：1170 K

文摘

•: Submicron P3HT and PBT layers on gold foil were investigated by chip calorimetry.
•: Isothermal studies inside/below T_g were performed while scanning at 30 000 K s⁻¹.
•: An important influence of the glass phase on crystallization is observed.
•: For P3HT imperfect crystals are formed that undergo isothermal perfectioning.
•: PBT reorders during heating, forming much more stable crystals.

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