Structural and magnetic phase diagram of YMn2−xFex(H,D)y compounds (5 ≤ y ≤ 6) synthesized under high H or D gaseous pressure
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YMn2−xFex(H,D)y compounds (5 ≤ y ≤ 6) were synthesized under high H or D pressure.

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Their structural and magnetic phase diagrams were determined versus Fe content.

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They form complex hydrides with YMn2H6 type structure for x < 1.

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They form interstitial hydrides with cubic or orthorhombic structures for x > 0.2.

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A large H/D isotope effect is observed on interstitial compound cell volumes.

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