A series of ionic cross-linked PEMs based on SPES and QGO were successfully prepared.
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Composite membranes showed enhanced mechanical properties, low swelling ratio and methanol permeability.
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SPES-10-QGO had minimum swelling ratio and water uptake with high proton conductivity of at 80 °C.
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Our strategy provided a promising strategy for constructing cross-linked PEMs with comprehensive performances.
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