Preparation of surface imprinted material of single enantiomer of mandelic acid with a new surface imprinting technique and study on its chiral recognition and resolution properties

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Preparation of surface imprinted material of single enantiomer of mandelic acid with a new surface imprinting technique and study on its chiral recognition and resolution properties

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作者：Baojiao Gao ; ^{gaobaojiao@126.com" class="auth_mail" title="E-mail the corresponding author} ; Lulu Chen ^{chenlulu@163.com" class="auth_mail" title="E-mail the corresponding author} ; Yanbin Li ^{liyanbin@126.com" class="auth_mail" title="E-mail the corresponding author}
关键词：Mandelic acid ; Hydroxyethyl methylacrylate ; Molecule surface imprinting ; Chiral recognition ; Chiral resolution
刊名：Journal of Chromatography A
出版年：2016
出版时间：22 April 2016
年：2016
卷：1443
期：Complete
页码：10-20
全文大小：2559 K

文摘

class="label">•: A surface initiating system of −SH/BPO was constituted on interface of SiO₂ particles and solution.
class="label">•: A new surface imprinting method of synchronously graft-polymerizing and imprinting was utilized.
class="label">•: A surface imprinted material of the single enantiomer of mandelic acid was successfully prepared.
class="label">•: (R)-Mandelic acid imprinted material has excellent enantiomeric recognition ability.
class="label">•: This (R)-enantiomer imprinted material has good chiral resolution ability for raceme.