Application of gas phase cryogenic vibrational spectroscopy to characterize the CO₂, CO, N₂ and N₂O interactions with the open coordination site on a Ni(I) macrocycle using dual cryogenic ion traps

详细信息    查看全文

• 作者：Stephanie M. Craig ; Fabian S. Menges ; Mark A. Johnson ; ^{mark.johnson@yale.edu}
• 关键词：Ion trap infrared spectroscopy ; Reaction intermediates ; Gas phase organometallic coordination compounds
• 刊名：Journal of Molecular Spectroscopy
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：332
• 期：Complete
• 页码：117-123
• 全文大小：1390 K
• 卷排序：332

文摘

Complex formation with two temperature-controlled RF ion traps. Small molecule activation by docking to an open coordination site of a Ni(I) compound. Mass selective vibrational predissociation spectroscopy reveals distortions of. Proof of the asymmetric nature of the CO2 binding motif by isotopic labeling.