New types of charge-compensated metallacarboranes: Synthesis, characterization, and structural studies of [(η<sup>5</sup>-RC<sub>2</sub>B<sub>9</sub>H<sub>9</sub>CH<sub>2</sub>NMe<sub>2</sub>)Cr(μ-Cl)Cl]<sub>2</sub> (R = H, Me)

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New types of charge-compensated metallacarboranes: Synthesis, characterization, and structural studies of [(η⁵-RC₂B₉H₉CH₂NMe₂)Cr(μ-Cl)Cl]₂ (R = H, Me)

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作者：Sang Ook Kang^a ; Jong-Dae Lee^b ; ^{jdlee@chosun.ac.kr" class="auth_mail" title="E-mail the corresponding author}
关键词：Metallacarborane ; Charge-compensated metal complexes ; Chromium ; Hydrogen bond ; X-ray crystallography
刊名：Journal of Organometallic Chemistry
出版年：2015
出版时间：1 December 2015
年：2015
卷：798
期：part_P1
页码：121-124
全文大小：461 K

文摘

•: The novel charge-compensated Cr(III) dicarbollide complexes have been synthesized.
•: A new transmetalation route via an aluminum dicarbollide was investigated.
•: The molecular structure was analyzed by single crystal X-ray diffraction.
•: The classical and non-classical intramolecular hydrogen bonds were observed.

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