Monomeric versus dimeric arrangement in the solid-state structures of pyridine adducts of lithium derivatives of two primary phosphanes

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• 作者：Rabe ; Gerd W. ; Guzei ; Ilia A. ; Rheingold ; Arnold L.
• 关键词：Lithium ; Alkali-metals ; Phosphanides ; Crystal structures
• 刊名：Inorganica Chimica Acta
• 出版年：2001
• 出版时间：April 27, 2001
• 年：2001
• 卷：315
• 期：2
• 页码：254-257
• 全文大小：105 K

文摘

The syntheses and X-ray crystal structure determinations of ^tBu₃C₆H₂P(H)Li(py)₃ (1) and [DmpP(H)Li(py)]₂ (2) (Dmp=2,6-dimesitylphenyl) are reported. Complex 1 crystallizes in the monoclinic space group P2₁/c. Crystal data for 1 at 243 K: a