Excitation-dependent variation in local symmetry in Ba2Mg(BO3)2 evidenced by Eu3+ luminescent structural probe
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文摘

Excitation wavelength-dependent emission characteristics of Eu3+ in Ba2Mg(BO3)2.

Equally intense magnetic and electric dipole transitions under long wavelength excitations.

Predominant magnetic dipole transition when excited using Eu3+–O2− charge transfer energy.

Atomic reorganization in the excited state changes the local site symmetry as evidenced by Eu3+ luminescent probe.

Eu3+ site symmetry changes from non-inversion to inversion symmetry in Ba2Mg(BO3)2.

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