PM2.5 mass concentration and oxidative potential (OP) varied markedly across Europe.
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The I/O PM2.5 mass concentration ratio was less than one with two exceptions.
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Generally, it is better to stay indoors than outdoors regarding particulate OP.
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OP metrics were associated mainly with traffic-related trace elements (e.g., Cu).
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Indoor air chemistry may play an important role in the OP of indoor PM.
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