Lanthanum-doped PZT synthesized by the oxidant peroxide method and sintered by conventional and microwave routes

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• 作者：Mayra D. Gonç ; alves ; Emerson R. Camargo ; ^{camargo@ufscar.br}
• 关键词：Wet-chemical synthesis ; PLZT ; Microwave sintering ; OPM route
• 刊名：Ceramics International
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：43
• 期：3
• 页码：3004-3009
• 全文大小：1289 K
• 卷排序：43

文摘

Lanthanum-doped lead zirconate titanate (Pb0.95La0.05Zr1−xTixO3) with two different compositions, x=0.20 (PLZT20) and 0.80 (PLZT80), were successfully obtained by the oxidant peroxide method (OPM). This environmental friendly synthetic route showed to be very attractive to prepare lead based ferroelectric powders since no carbon or halides compounds were used. Tetragonal perovskite structure was observed for PLZT80 and rhombohedral perovskite for PLZT20, with single phase identified in the powders calcined at temperatures higher than 700 °C. Powders crystallized at 700 °C were used to produce ceramic samples that were sintered at 1000 °C for 2 h by conventional and microwaves techniques. The composition of the fractured surface of ceramics were quite close to the nominal molar composition, indicating that the OPM promotes the formation of materials with high compositional homogeneity and similar microstructures regardless the sintering method used.