Performance of a Fe-N-C catalyst for the oxygen reduction reaction in direct methanol fuel cell: Cathode formulation optimization and short-term durability

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Performance of a Fe-N-C catalyst for the oxygen reduction reaction in direct methanol fuel cell: Cathode formulation optimization and short-term durability

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作者：Luigi Osmieri^a ; ^b ; ^{luigi.osmieri@polito.it" class="auth_mail" title="E-mail the corresponding author} ; Ricardo Escudero-Cid^b ; ^{ricardo.escudero@uam.es" class="auth_mail" title="E-mail the corresponding author} ; Alessandro H.A. Monteverde Videla^a ; ^{alessandro.monteverdevidela@polito.it" class="auth_mail" title="E-mail the corresponding author} ; Pilar Oc&oacute ; n^b ; ^{pilar.ocon@uam.es" class="auth_mail" title="E-mail the corresponding author} ; Stefania Specchia^a ; ^{stefania.specchia@polito.it" class="auth_mail" title="E-mail the corresponding author}
关键词：Non-noble metal catalyst ; Iron-phthalocyanine ; Oxygen reduction reaction ; Rotating ring-disk electrode ; Direct methanol fuel cell
刊名：Applied Catalysis B: Environmental
出版年：2017
出版时间：February 2017
年：2017
卷：201
期：Complete
页码：253-265
全文大小：2761 K

文摘

ass="label">•: ar0005">A non-noble metal catalyst for ORR was synthesized from Fe(II)-phthalocyanine.
ass="label">•: ar0010">High ORR activity and selectivity for direct 4-electrons reduction to H₂O.
ass="label">•: ar0015">High methanol tolerance and good potential candidate for DMFC cathode application.
ass="label">•: ar0020">Optimization of electrode formulation regarding catalyst load and Nafion^® content.
ass="label">•: ar0025">Higher durability in DMFC compared to Pt/C catalyst in short term test (3 h).