Chiral separation by a terminal chirality triggered P-helical quinoline oligoamide foldamer

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Chiral separation by a terminal chirality triggered P-helical quinoline oligoamide foldamer

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作者：Hiroki Noguchi^a ; ^b ; ^c ; Makoto Takafuji^a ; Victor Maurizot^b ; ^c ; Ivan Huc^b ; ^c ; ^{i.huc@iecb.u-bordeaux.fr" class="auth_mail" title="E-mail the corresponding author} ; Hirotaka Ihara^a ; ^d ; ^{ihara@kumamoto-u.ac.jp" class="auth_mail" title="E-mail the corresponding author}
关键词：Chiral stationary phase ; Enantioselectivity ; Helical structure ; Aromatic foldamers ; Chiral HPLC
刊名：Journal of Chromatography A
出版年：2016
出版时间：11 March 2016
年：2016
卷：1437
期：Complete
页码：88-94
全文大小：1052 K

文摘

•: A quinoline oligoamide-grafted silica was synthesized as an HPLC stationary phase.
•: The oligoamide adopted a helical chiral secondary structure on the silica surface.
•: This new stationary phase showed enantioselectivity toward chiral aromatic compounds.
•: Extremely high selectivity was observed toward same handedness of quinoline oligomers.

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