Tris(trifluoromethyl)germylethynyl derivatives of biphenyl and anthracene: Synthesis, structure, and evidence of the intramolecular charge transfer on the germanium center

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Tris(trifluoromethyl)germylethynyl derivatives of biphenyl and anthracene: Synthesis, structure, and evidence of the intramolecular charge transfer on the germanium center

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作者：Nikolai L. Ermolaev^a ; ^{nick-ermolaev@yandex.ru" class="auth_mail" title="E-mail the corresponding author} ; Ilya V. Lenin^b ; Georgii K. Fukin^c ; Andrei S. Shavyrin^c ; Mikhail A. Lopatin^c ; Olga V. Kuznetsova^c ; Boris A. Andreev^d ; ^e ; Denis I. Kryzhkov^d ; ^e ; Stanislav K. Ignatov^e ; Evgeny P. Chuhmanov^e ; Nadezhda T. Berberova^f ; Konstantin P. Pashchenko^f
关键词：Germanium ; Charge transfer ; Conjugation ; Excited state ; Perfluoroalkyl
刊名：Journal of Organometallic Chemistry
出版年：2015
出版时间：15 November 2015
年：2015
卷：797
期：Complete
页码：83-95
全文大小：2470 K

文摘

•: Some model of tris(trifluoromethyl)germyl derivatives have been prepared.
•: Unusually intramolecular energy and electron-transfer have been found.
•: Vacant Ge 4d atomic orbitals play a key role in this phenomenon.