A rapid and convenient synthesis of gem-bis(dithiocarbamate) derivatives from primary aliphatic amines, carbon disulfide, and aromatic aldehydes using boron trifluoride-diethyl etherate

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• 作者：Firouzeh Nemati^a ; ^{fnemati_1350@yahoo.com" class="auth_mail} ; ^{fnemati@semnan.ac.ir" class="auth_mail} ; Ali Ghorbani Gharjeh Ghiyaei^a ; Behrouz Notash^b ; Mojtaba Hajiloo Shayegan^c ; Vahid Amani^d
• 关键词：Dithiocarbamic acid salt ; Primary aliphatic amine ; Carbon disulfide ; Boron trifluoride-diethyl etherate
• 刊名：Tetrahedron Letters
• 出版年：18 June 2014
• 年：2014
• 卷：55
• 期：25
• 页码：3572-3575
• 全文大小：601 K

文摘

An efficient route for the synthesis of gem-bis(dithiocarbamate) derivatives is developed using dithiocarbamic acid salts generated from primary aliphatic amines and CS₂. The method offers high yields, employs mild reaction conditions, and demonstrates excellent functional group compatibility. The structures of the products were confirmed spectroscopically and by X-ray analysis.