Combined AAs generated more CF but less DCAN than free AAs during chlorination.
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The pH had greater effect on combined AAs than free AAs during chlorination.
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AAs generated less DBPs especially DCAN during chloramination than chlorination.
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More bromine merged into THMs than DHANs during chlorination of combined AAs.
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Peptide bonds in combined AAs affected formation of DBPs during chlorination.
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