An integrated experimental and quantum chemical study on the complexation properties of (9′-fluorene)-spiro-5-hydantoin and its thioanalogue

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An integrated experimental and quantum chemical study on the complexation properties of (9′-fluorene)-spiro-5-hydantoin and its thioanalogue

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作者：Anife Ahmedova^a ; ^{Ahmedova@chem.uni-sofia.bg" class="auth_mail" title="E-mail the corresponding author} ; Petja Marinova^b ; Marin Marinov^c ; Neyko Stoyanov^d
关键词：(9&prime ; -fluorene)-spiro-5-hydantoin ; Thio-hydantoins ; Cu(II) complexes ; EPR ; Quantum chemical calculations
刊名：Journal of Molecular Structure
出版年：2016
出版时间：15 March 2016
年：2016
卷：1108
期：Complete
页码：602-610
全文大小：1012 K

文摘

•: fluorene-spiro-5-hydantoins form Cu(II) complexes only in presence of a strong base.
•: experimental and DFT-calculated EPR parameters allowed for geometry verification.
•: Electronic and structural effects on the complexation abilities of spiro-hydantoins.

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