Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides

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• 作者：Anand Pariyar^a ; Suranjana Bose^a ; Achintesh Narayan Biswas^b ; Purak Das^a ; Pinaki Bandyopadhyay^a ; ^{pbchem@rediffmail.com}
• 关键词：5 ; 10 ; 15-tris(difluorophenyl)iron(IV) corrole ; Catalysis ; Oxygenation ; t-Butyl hydroperoxide ; Cyclohexylhydroperoxide
• 刊名：Catalysis Communications
• 出版年：2013
• 出版时间：5 February, 2013
• 年：2013
• 卷：32
• 期：Complete
• 页码：23-27
• 全文大小：782 K

文摘

The catalytic properties of 5,10,15-tris(difluorophenyl)iron(IV) corrole complex [(tdfc)Fe^IVCl] (1) with tert-butylhydroperoxide as the terminal oxidant was evaluated. The 1/t-BuOOH system has been found to catalyze the oxidation of alkanes, alkenes, alkylbenzene and alcohols at room temperature. The homolytic cleavage of the OO bond of tert-butylhydroperoxide by catalyst 1 was observed and the oxygenates have been shown to be derived from organoperoxides. Selective hydroxylation of unactivated CH bonds of alkanes has also been realized using catalyst 1 with m-chloroperbenzoic acid as the oxidant.