文摘
Room temperature acid sonication of milk samples is proposed as a fast alternative methodology for the determination of the total content of 45 elements (Li, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Rb, Sr, Y, Mo, Ag, Cd, In, Sn, U, Sb, Te, Cs, Ba, Hg, Pb, Bi, Th, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Hf and Ta) in milk by inductively coupled plasma mass spectrometry (ICP-MS). The aforementioned procedure involves a 10min sample pre-treatment. Measurements were made in quantitative and semiquantitative (Totalquant®) modes of analysis using Rh as internal standard and Be, Ge, Tb and Re for internal calibration of the equipment in the semiquantitative mode. The selected isotopes were in general the most abundant ones of each element, except in cases where polyatomic or isobaric interferences were detected. Results of total concentrations in 10 liquid and 11 powdered commercially available milk samples were presented. Method validation was performed by measuring a SRM NIST-1549 non-fat milk powder and through the use of recovery experiments. Additionally, the proposed methodology was compared with a method based on a previous microwave-assisted digestion of samples and a direct analysis of 1:4 diluted samples.
