The factors that influence solubility in perfluoroalkane solvents

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The factors that influence solubility in perfluoroalkane solvents

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作者：Michael H. Abraham^a ; ^{m.h.abraham@ucl.ac.uk" class="auth_mail" title="E-mail the corresponding author} ; William E. Acree^b ; Enrico Matteoli^c
关键词：Perfluoroalkanes ; Hydrophobic effects ; Solubility ; Partition coefficients ; Abraham descriptors ; Linear free energy relationship ; Principal component analysis ; Scaled particle theory
刊名：Fluid Phase Equilibria
出版年：2016
出版时间：15 August 2016
年：2016
卷：421
期：Complete
页码：59-66
全文大小：378 K

文摘

•: Data on solvation of solutes in perfluoroalkane solvents collected.
•: Gas-perfluoroalkane partition coefficients, K, analysed.
•: The main influence on log K is a solute size effect.
•: The size effect is a combination of cavity and interaction effects.
•: Cavity effects calculated by Scaled Particle Theory.

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