Understanding the influence of hydrocarbon insulators in fluorinated amines: Reactivity of poly(hexafluoropropylene oxide) amine containing methylene spacers

详细信息    查看全文

• 作者：Chadron M. Friesen ; Jon L. Howell ; Ashley Jamieson ; Daryl A. Nyvall
• 关键词：Poly(hexafluoropropylene oxide) ; Amines ; Perfluoropolyalkylethers
• 刊名：Journal of Fluorine Chemistry
• 出版年：2008
• 出版时间：March 2008
• 年：2008
• 卷：129
• 期：3
• 页码：193-203
• 全文大小：797 K

文摘

Although reactions involving hydrocarbon amines have been thoroughly investigated, very little is currently known about reactions of corresponding fluorinated amines containing a methylene spacer group. Furthermore, such reactions involving the poly(hexafluoropropylene oxide) (herein, polyHFPO) amine have been completely unexplored. The addition of acyl, sulfonyl and alkyl halides, isocyanates, aldehydes, anhydrides and esters to polyHFPO amine has been accomplished. The results of these reactions, including reaction mechanisms, yields, byproducts, etc. are discussed.