Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane

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• 作者：Zdenek Spichal ; Andrej Jancarik ; Ctibor Mazal ; Jiri Pinkas ; Pavla Pekarkova ; Marek Necas
• 关键词：Bicyclopentanes ; Lanthanides ; Coordination polymers ; X-ray crystallography
• 刊名：Polyhedron
• 出版年：2013
• 出版时间：7 October, 2013
• 年：2013
• 卷：62
• 期：Complete
• 页码：83-88
• 全文大小：748 K

文摘

The reaction of 1,3-bis(diphenylphosphoryl)bicyclo[1.1.1]pentane (1) with lanthanide nitrates provided a series of layered network coordination polymers Ln(1)_1.5(NO₃)₃ (Ln = Ce, Pr, Nd, Eu, Tb, Er, Yb, Lu). Crystal structures of all members of the series were determined by single crystal X-ray diffraction and were found isostructural. The compounds were studied by IR spectroscopy, luminescence spectroscopy, thermal analysis (TG/DSC) and powder X-ray diffraction (PXRD) techniques.