Shear induced weakening of the hydrogen bonding lattice of the energetic material 5,5′-Hydrazinebistetrazole at high-pressure

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• 作者：Jennifer A. Ciezak-Jenkins ; ^{jennifer.a.ciezak-jenkins.civ@mail.mil} ; Timothy A. Jenkins
• 关键词：High-pressure ; Diamond anvil cell ; Energetic materials ; Vibrational spectroscopy
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：1129
• 期：Complete
• 页码：313-318
• 全文大小：1530 K
• 卷排序：1129

文摘

HBTA was studied by in-situ XRD and vibrational spectroscopy to near 25 GPa. The monoclinic structure persisted over the pressure range studied. Geometry modifications occur in the hydrogen bonding lattice with compression. Blue shifts of the NH stretching modes were noted, implying a weakening H-bond.