Thermodynamics of hydrogen bonding and van der Waals interactions of organic solutes in solutions of imidazolium based ionic liquids: “Structure-property” relationships

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Thermodynamics of hydrogen bonding and van der Waals interactions of organic solutes in solutions of imidazolium based ionic liquids: “Structure-property” relationships

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作者：Mikhail A. Varfolomeev ; ^{vma.ksu@gmail.com" class="auth_mail" title="E-mail the corresponding author} ; ^{mikhail.varfolomeev@kpfu.ru" class="auth_mail" title="E-mail the corresponding author} ; Artashes A. Khachatrian ; Bulat S. Akhmadeev ; Boris N. Solomonov
关键词：Hydrogen bond ; van der Waals interactions ; Solution calorimetry ; Enthalpy of solution ; Enthalpy of solvation ; Ionic liquid ; Solvent scale
刊名：Thermochimica Acta
出版年：2016
出版时间：10 June 2016
年：2016
卷：633
期：Complete
页码：12-23
全文大小：1260 K

文摘

•: Solution enthalpies of organic solutes in imidazolium based ionic liquids were measured.
•: van der Waals interactions scale of imidazolium based ionic liquids was proposed.
•: Enthalpies of solvation of organic solutes in ionic liquids were determined.
•: Hydrogen bond enthalpies of organic solutes with ionic liquids were calculated.
•: Relationships between structure of ionic liquids and thermochemical data were obtained.