Molecular paramagnets. The effect of structural modification on (porphyrinato) gadolinium(III) magnetothermal properties

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Molecular paramagnets. The effect of structural modification on (porphyrinato) gadolinium(III) magnetothermal properties

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作者：Victor V. Korolev ; Tatyana N. Lomova ; ^{tnl@isc-ras.ru" class="auth_mail" title="E-mail the corresponding author} ; ^{tnl50@mail.ru" class="auth_mail" title="E-mail the corresponding author} ; Anna G. Ramazanova ; Elena G. Mozhzhukhina
关键词：Porphyrins ; Rare earths ; Magnetоthermal properties ; Magnetocaloric effect ; Structure effect
刊名：Synthetic Metals
出版年：2016
出版时间：October 2016
年：2016
卷：220
期：Complete
页码：502-507
全文大小：880 K

文摘

ass="label">•: ar0005">Magnetothermal properties of (5,10,15,20-tetraphenyl21H,23H-porphinato) gadolinium(III) acetylacetonate are studied for the first time.
ass="label">•: ar0010">Magnetocaloric effect in (Acac)GdTPP of 0.38 K at ΔB 0–1 T and T 278 K is only slightly lower than in polycrystalline gadolinium and gadolinium ferrite.
ass="label">•: ar0015">The effect of axial acetylacetonate on magnetothermal properties is established in a view of application in cooling and hyperthermia.

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