Synthesis and characterization of perfluorohexylated poly(3,4-ethylenedioxythiophene)

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• 作者：Zuo ; Liangbin ; Qing ; Feng-Ling ; Meng ; Wei-Dong ; Huang ; Xiaoyu ; Zhang ; Sen ; Wu ; Qiang
• 关键词：Perfluorohexylated poly(3 ; 4-ethylenedioxythiophene) ; Oxidative chemical polymerization ; Electrochemical polymerization
• 刊名：Journal of Fluorine Chemistry
• 出版年：2004
• 出版时间：October, 2004
• 年：2004
• 卷：125
• 期：10
• 页码：1441-1446
• 全文大小：324 K

文摘

The perfluorohexylated 3,4-ethylenedioxythiophene 5 was prepared via Mitsunobu reaction of perfluorohexylatyed diol 2 with diethyl 3,4-dihydroxythiophenedicarboxylate followed by decarboxylation. The polymerization of 5 was conducted with both oxidative chemical and electrochemical polymerizations. The polymers were characterized by cyclic voltammogram, UV, IR, TGA and DSC.