Preparation, structures and properties of manganese complexes containing amine-(amido or amidato)-phenolato type ligands

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Preparation, structures and properties of manganese complexes containing amine-(amido or amidato)-phenolato type ligands

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作者：Ryoji Mitsuhashi^a ; ^b ; Rina Ogawa^a ; Ryuta Ishikawa^c ; Takayoshi Suzuki^a ; ^d ; ^{suzuki@okayama-u.ac.jp" class="auth_mail" title="E-mail the corresponding author} ; Yukinari Sunatsuki^a ; Satoshi Kawata^c
关键词：Tridentate amide ligands ; Methoxido-bridged complexes ; Tetranuclear manganese cluster ; Magnetic behavior ; Crystal structure
刊名：Inorganica Chimica Acta
出版年：2016
出版时间：1 June 2016
年：2016
卷：447
期：Complete
页码：113-120
全文大小：1744 K

文摘

•: Dinuclear methoxido-bridged Mn^III complexes having amine–amidato–phenolato type ligands were characterized.
•: A tetranuclear methoxido-bridged Mn^II₂Mn^III₂ complex was determined by X-ray analysis.
•: Magnetic behavior was changed drastically when the crystals of the Mn/HL3 complex were efflorescent.

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