Microwave-assisted low temperature synthesis of wurtzite ZnS quantum dots

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• 作者：Robina Shahid ; ^rkhan@kth.se ; Muhammet S. Toprak ; ^{toprak@kth.se} ; Mamoun Muhammed
• 关键词：Nanostructure ; Semiconductors ; Quantum dots ; Microwave ; Chemical synthesis ; Optical properties
• 刊名：Journal of Solid State Chemistry
• 出版年：2012
• 出版时间：March 2012
• 年：2012
• 卷：187
• 期：Complete
• 页码：130-133
• 全文大小：584 K

文摘

In this work we report, for the first time, on microwave assisted synthesis of wurtzite ZnS quantum dots (QDs) in controlled reaction at temperature as low as 150 ¡ãC. The synthesis can be done in different microwave absorbing solvents with multisource or single source precursors. The QDs are less than 3 nm in size as characterized by transmission electron microscopy (TEM) using selected area electron diffraction (SAED) patterns to confirm the wurtzite phase of ZnS QDs. The optical properties were investigated by UV-Vis absorption which shows blue shift in absorption compared to bulk wurtzite ZnS due to quantum confinement effects. The photoluminescence (PL) spectra of QDs reveal point defects related emission of ZnS QDs.