Luminescence, magnetic and vibrational properties of novel heterometallic niccolites [(CH3)2NH2][CrIIIMII(HCOO)6] (MII=Zn, Ni, Cu) and [(CH3)2NH2][AlIIIZnII(HCOO)6]:Cr3+

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Luminescence, magnetic and vibrational properties of novel heterometallic niccolites [(CH₃)₂NH₂][Cr^IIIM^II(HCOO)₆] (M^II=Zn, Ni, Cu) and [(CH₃)₂NH₂][Al^IIIZn^II(HCOO)₆]:Cr³⁺

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作者：Mirosław Mączka ; ^{m.maczka@int.pan.wroc.pl" class="auth_mail" title="E-mail the corresponding author} ; Adam Pietraszko ; Adam Pikul ; Krzysztof Hermanowicz
关键词：Metal organic framework ; Magnetization ; Luminescence ; Infrared ; Raman
刊名：Journal of Solid State Chemistry
出版年：2016
出版时间：January 2016
年：2016
卷：233
期：Complete
页码：455-462
全文大小：1424 K

文摘

ass="label">•: Novel chromium- and aluminum-based MOF compounds have been synthesized.
ass="label">•: These heterometallic compounds crystallize in niccolite-type architecture.
ass="label">•: Magnetization measurement revealed ferromagnetic ordering at low temperatures.
ass="label">•: IR and Raman spectra were measured and assignment of modes has been proposed.
ass="label">•: The compounds exhibit efficient chromium-based luminescence.