Photodegradation of the azole fungicide climbazole by ultraviolet irradiation under different conditions: Kinetics, mechanism and toxicity evaluation

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Photodegradation of the azole fungicide climbazole by ultraviolet irradiation under different conditions: Kinetics, mechanism and toxicity evaluation

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作者：Wang-Rong Liu ; Guang-Guo Ying ; ^{guang-guo.ying@gig.ac.cn" class="auth_mail" title="E-mail the corresponding author} ; ^{guangguo.ying@gmail.com" class="auth_mail" title="E-mail the corresponding author} ; Jian-Liang Zhao ; You-Sheng Liu ; Li-Xin Hu ; Li Yao ; Yan-Qiu Liang ; Fei Tian
关键词：Climbazole ; Photodegradation ; Reactive oxygen species ; By-products ; Toxicity
刊名：Journal of Hazardous Materials
出版年：2016
出版时间：15 November 2016
年：2016
卷：318
期：Complete
页码：794-801
全文大小：1983 K

文摘

•: Climbazole (CZ) could be effectively degraded under UV-254 irradiation.
•: CZ underwent direct and self-sensitized photolysis involving ROS.
•: The main photodegradation by-products of CZ were identified and semi-quantitated.
•: Pathway includes hydroxylative dechlorination, dechlorination, and de-pinacolone.
•: The toxicity of the photodegradation system reduced after UV-254 irradiation.

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