Ag/titanate and Ag/titanate-CNT are fabricated using deposition-photo-irradiation process.
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Ag/titanate exhibited the highest performance towards MOR.
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Strong metal–support interactions exist between Ag particles and titanate support.
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The enhancement was due to the high surface area and the modified electron structure.
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Electrocatalytic enhancement for Ag/titanate is mainly via bifunctional mechanism.
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