Development of a highly α-regioselective indium-mediated allylation reaction in water

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• 作者：Loh ; Teck-Peng ; Tan ; Kui-Thong ; Yang ; Jian-Ying ; Xiang ; Chao-Li
• 刊名：Tetrahedron Letters
• 出版年：2001
• 出版时间：December 3, 2001
• 年：2001
• 卷：42
• 期：49
• 页码：8701-8703
• 全文大小：56.3 K

文摘

Linear α homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this paper.