Optical non-linearity tuning in Ca<sub>8-x</sub>Pb<sub>x</sub>MBi(VO<sub>4</sub>)<sub>7</sub> whitlockite-type systems

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Optical non-linearity tuning in Ca_8-xPb_xMBi(VO₄)₇ whitlockite-type systems

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作者：Daria A. Beskorovaynaya^a ; ^b ; ^{darya.beskorovajnaya@list.ru" class="auth_mail" title="E-mail the corresponding author} ; Dina V. Deyneko^a ; ^c ; Oksana V. Baryshnikova^a ; Sergey Yu. Stefanovich^a ; ^d ; Bogdan I. Lazoryak^a
关键词：Crystal structure ; X-ray diffraction ; Nonlinear optics ; Phase transitions
刊名：Journal of Alloys and Compounds
出版年：2016
出版时间：25 July 2016
年：2016
卷：674
期：Complete
页码：323-330
全文大小：1336 K

文摘

•: The Curie temperatures of ferroelectric Ca_8-xPb_xMBi(VO₄)₇ solid solutions are chemically controlled from 1070 down to 730–800 K.
•: Optical SHG non-linear coefficient in Ca_8-xPb_xMBi(VO₄) strongly increase up to 3.3 pm/V at an optimized Pb and Bi concentration.
•: Structure-property correlations in the whitlockites includes crystal site positions occupancy by two- and trivalent cations.

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