Degradation of tris(2-chloroethyl) phosphate by ultraviolet-persulfate: Kinetics, pathway and intermediate impact on proteome of Escherichia coli

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Degradation of tris(2-chloroethyl) phosphate by ultraviolet-persulfate: Kinetics, pathway and intermediate impact on proteome of Escherichia coli

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作者：Hua-se Ou^a ; Juan Liu^a ; Jin-shao Ye^a ; ^b ; ^{jinshaoye@lbl.gov" class="auth_mail" title="E-mail the corresponding author} ; ^{folaye@126.com" class="auth_mail" title="E-mail the corresponding author} ; Lin-lin Wang^a ; ^b ; Nai-yun Gao^c ; Jing Ke^b
关键词：Organophosphorus flame retardants ; Ultraviolet ; Persulfate ; Advanced oxidation process ; Proteomics
刊名：Chemical Engineering Journal
出版年：2017
出版时间：15 January 2017
年：2017
卷：308
期：Complete
页码：386-395
全文大小：1738 K

文摘

•: 254 nm ultraviolet/persulfate induces rapid degradation of TCEP.
•: Three intermediates are generated by selective electron-transfer of SO₄⁻.
•: The impact of TCEP and intermediates on E. coli protein expression is compared.
•: Degrading TCEP induces less stress on E. coli than intact CIP.
•: The SO₄⁻-based incomplete degradation reduces the toxicity of TCEP.

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