Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation

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• 作者：Danila Vasilchenko^a ; ^b ; ^{vasilchenko@niic.nsc.ru} ; Sergey Tkachev^a ; Iraida Baidina^a ; Galina Romanenko^c ; Sergey Korenev^a ; ^b
• 关键词：Platinum ; O-ligands ; Diazacrown ; Crystal structure ; NMR
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：1130
• 期：Complete
• 页码：855-859
• 全文大小：735 K
• 卷排序：1130

文摘

Protonated diazacrown selectively isolates platinum(IV) homoleptic complexes. Intensive H-bonding connects the macrocycle and platinum(IV) complexes. Condensation of platinum nitrato complexes can be suppressed by diazacrown.