A BiOCl/TiO2 hierarchical composite was synthesized at the presence of PVP.
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The PVP plays an important role for enhancing the photoactivity.
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This hierarchical composite exhibits enhanced photoactivity and photostability.
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This hierarchical composite exhibits rapid migration of the interface charges.
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This BiOCl/TiO2 heterojunction exhibits superior visible-light absorption ability.
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