KOH-promoted Pt/Al<sub>2</sub>O<sub>3</sub> catalysts for water gas shift and methanol steam reforming: An operando DRIFTS-MS study

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KOH-promoted Pt/Al₂O₃ catalysts for water gas shift and methanol steam reforming: An operando DRIFTS-MS study

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作者：Andre Kaftan^a ; ^{andre.kaftan@fau.de" class="auth_mail" title="E-mail the corresponding author} ; Matthias Kusche^b ; ^{matthias.kusche@crt.cbi.uni-erlangen.de" class="auth_mail" title="E-mail the corresponding author} ; Mathias Laurin^a ; ^{mathias.laurin@fau.de" class="auth_mail" title="E-mail the corresponding author} ; Peter Wasserscheid^b ; ^c ; ^{peter.wasserscheid@fau.de" class="auth_mail" title="E-mail the corresponding author} ; Jö ; rg Libuda^a ; ^c ; ^{joerg.libuda@fau.de" class="auth_mail" title="E-mail the corresponding author}
关键词：Infrared spectroscopy ; Online mass spectrometry ; Platinum ; Water-gas shift ; Methanol steam reforming
刊名：Applied Catalysis B: Environmental
出版年：2017
出版时间：February 2017
年：2017
卷：201
期：Complete
页码：169-181
全文大小：4482 K

文摘

•: WGS and MSR are investigated on alumina-supported Pt catalysts.
•: Significantly improved activity and selectivity by applying a thin KOH-coating.
•: Strong modification of Pt by doping with K.
•: Hygroscopicity and basicity of KOH essential for enhanced performance.
•: Reaction pathway influenced by coating.

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