Opal-like array of polystyrene (PS) microspheres is synthesized by self-assembly.
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This periodic PS array is used as a rapid sensor for methanol and ethanol.
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Solvents are detected by routes of reflection coordinates in chromaticity diagram.
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They are also detected directly by naked eye based on change in color of sensor.
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The color change is irreversible for methanol but reversible for ethanol.
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