Seafloor-precipitated carbonate fans in the Neoproterozoic Rainstorm Member, Johnnie Formation, Death Valley Region, USA

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• 作者：Sara Brady Pruss ; Frank A. Corsetti ; Woodward W. Fischer
• 关键词：Aragonite ; Precipitates ; Ediacaran ; Carbon cycle
• 刊名：Sedimentary Geology
• 出版年：2008
• 出版时间：30 June 2008
• 年：2008
• 卷：207
• 期：1-4
• 页码：34-40
• 全文大小：1337 K

文摘

Cm-sized carbonate seafloor fans occur in the Neoproterozoic Rainstorm Member of the Johnnie Formation, Death Valley, USA. The fans formed in a mixed carbonate-clastic succession near storm wave base at the base of parasequences on a storm-dominated ramp. Petrographic observations indicate that the fans were originally precipitated as aragonite and later inverted to calcite during diagenesis. Although not directly dated, the Rainstorm Member preserves a large magnitude negative carbon isotopic anomaly (down to − 11‰ PDB) tentatively correlated to the largest known carbon isotope excursion found in many stratigraphic successions around the world between 585 Ma and 550 Ma. Thus, the age distribution of seafloor aragonite fans in Neoproterozoic strata appears more widespread than previously thought, occurring in strata significantly younger than the last widespread Neoproterozoic glaciation. Rainstorm Member carbonate fans and oolitic units (representing time-correlative shallower environments) record similar carbon isotope ratios during the negative carbon isotopic anomaly. The carbon isotopic homogeneity displayed between fans and other carbonate sediments implies that waters across the shelf were well-mixed rather than stratified during the late Neoproterozoic isotopic anomaly. In addition, the similarity of carbon isotope ratios shared among fans along a stratigraphic horizon (on a m- to cm-scales) suggests that the local source of alkalinity required for fan growth was derived from a well-mixed reservoir, likely seawater, rather than local diagenetic fluids. Increased alkalinity and the presence of inhibitors to carbonate nucleation (perhaps Fe²⁺ under anoxic conditions) likely fostered precipitation of aragonite crystal fans on the seafloor.