Mixed matrix membranes based on UiO-66 MOFs in the polymer of intrinsic microporosity PIM-1
文摘
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Metal Organic Frameworks UiO-66 improve the performance of PIM-1 gas separation membranes.

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The separation performance of the MMMs exceeds the 2008 Robeson upper bound for various gas pairs.

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The effect of UiO-66 on PIM-1 can be described by the Maxwell model.

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Methanol treatment greatly enhances the permeability.

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Mixed gas permeation experiments confirm an excellent separation performance.

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