Vapor phase solvents loaded in zeolite as the sustainable medium for the preparation of Cu-BTC and ZIF-8

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• 作者：Yang Chen ; Chengyin Yang ; Xiaoqing Wang ; Jiangfeng Yang ; ^{yangjiangfeng@tyut.edu.cn} ; Jinping Li ; ^{jpli211@hotmail.com}
• 关键词：Metal&ndash ; organic frameworks ; Solvent recovery ; Solvent&ndash ; evaporated conversion ; Steam-assisted conversion ; Solid-phase reaction ; NH3 adsorption
• 刊名：Chemical Engineering Journal
• 出版年：2017
• 出版时间：1 April 2017
• 年：2017
• 卷：313
• 期：Complete
• 页码：179-186
• 全文大小：2272 K
• 卷排序：313

文摘

SEC and SAC methods have been developed to prepare Cu-BTC and ZIF-8 using a vapor phase solvents recovery strategy. Zeolite loading and removal of solvents can recycle solvents effectively and achieve green synthesis of MOFs. SEC and SAC processes exhibited different mechanisms during the multi-stage reaction and cladding diffusion reaction. The reverse result implied MOFs in NH3 adsorption applications should possess both high water uptake and stable structures.