Enhanced visible-light photocatalytic activity of carbonate-doped anatase TiO2 based on the electron-withdrawing bidentate carboxylate linkage
文摘

Carbonate-doped TiO2 was prepared via a hypoxic carbonization method.

A bidentate carboxylate linkage was formed between carbonate and TiO2 lattice.

The electron-withdrawing carboxylate ligands can remarkably narrow the bandgap.

Two possible mechanisms were elucidated based on the bidentate carboxylate linkage.

Carboxylate chelate carbonate-doped TiO2 shows high photodegradation activity.

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