Asymmetric total synthesis of (+)-monocerin

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• 作者：Bowen Fang ; Xingang Xie ; Huilin Li ; Peng Jing ; Jixiang Gu ; Xuegong She
• 关键词：UYFBNSFMKNJOJV-MRCXROJRSA-N ; VAYQNUBOZLPGDH-OLXJLDBKSA-N ; TXZSDPXEQWWPFA-YWPYICTPSA-N ; WRKWBVRAYPFGPS-ZOWXZIJZSA-N ; CUGFAGLMOPLERR-QPPBQGQZSA-N ; UHKYLMSTZPBUDL-MNOVXSKESA-N ; RKULLDUWEZQZJK-MSOLQXFVSA-N ; HRTXWJKALYWNHB-KNQAVFIVSA-N ; SSEYHAMTKLMEOO-JQVVWYNY
• 刊名：Tetrahedron Letters
• 出版年：2013
• 出版时间：20 November, 2013
• 年：2013
• 卷：54
• 期：47
• 页码：6349-6351
• 全文大小：387 K

文摘

A concise asymmetric total synthesis of (+)-monocerin has been accomplished. The cis-fused furobenzopyranone of monocerin was efficiently constructed via a Lewis acid-mediated stereoselective cyclization of 1,2,4-triols intermediate.