SnO2 nanowire arrays and pinecone-like nanoparticles are hydrothermally synthesized.
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The process is convenient and simple.
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The alkali-salt-ratio plays a key role in the morphology evolution.
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The PL spectra have been de-convoluted following the Gaussian profile fitting.
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A reasonable growth mechanism of as-prepared SnO2 nanostructures is proposed.
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